故事紧接着上一季，金钱的紧缺和癌症的侵袭都不再是沃尔特（布莱恩·科兰斯顿 Bryan Cranston 饰）将要面对的难解问题了，家庭的濒临破碎才是让沃尔特感到心痛的真正原因所在。由于妻子斯凯勒（安娜·古恩 Anna Gunn 饰）坚定的离婚决心，沃尔特从家中搬出，搬入了新的居所，这也为他和大毒枭古斯（吉安卡洛·埃斯珀西多 Giancarlo Esposito 饰）之间的合作创造了有利的条件。 为了替死去的图可（雷蒙德·克鲁兹 Raymond Cruz 饰）报仇，两位冷面杀手找到了汉克（迪恩·诺里斯 Dean Norris 饰），激烈的交锋后，汉克身负重伤。面对着逐渐失控的一切，沃尔特感到了前所未有的危机，尤其是他的新搭档盖尔（大卫·科斯塔贝尔 David Costabile 饰），沃尔特明白，一旦盖尔掌握了他独创的制毒技术，自己将很快被古斯除掉。
尼克频道热播剧《胜利之歌》(Victorious)和《爱卡莉》(iCarly)刚刚剧终不久，衍生剧《莎姆与小猫的新生活》(Sam & Cat)就开播了。这部情景喜剧围绕《爱卡莉》中Jennette McCurdy饰演的Sam和《胜利之歌》中Ariana Grande饰演的Cat两个女孩展开，两人在洛杉矶相遇，成为室友，并开始了做保姆赚钱的生意……
Zac is a teenage boy who decides to camp on Mako Island, unaware that three mermaids, Sirena, Nixie and Lyla, who are guardians of the island, are watching him. That night, when the full moon rises, the boy comes into contact with the magic water of the Moon Pool. The following morning, Zac wakes up discovering he has become a merman with a fish-like tail and the ability to control and manipulate water. His new-found merman abilities will cause problems for the mermaids.
The three mermaids, curious about living on land, are transformed into humans while in the moon pool during a full moon, now having the ability to live like humans.
